(tert-Butyl isocyanide-κC)trichloridogallium(III)
نویسندگان
چکیده
منابع مشابه
Tris(tert-butyl isocyanide-κC)carbonylnickel(0)
The title compound, [Ni(C(5)H(9)N)(3)(CO)], was prepared from Ni(CO)(4) and a tenfold excess of tert-butyl isocyanide. It crystallizes with two symmetry-independent mol-ecules per asymmetric unit. The central Ni atom of each independent mol-ecule has a nearly perfect tetra-hedral coordination environment, comprising one carbon monoxide and three isocyanide ligands. The title compound is the fir...
متن کاملPalladium-catalyzed chemoselective synthesis of indane-1,3-dione derivatives via tert-butyl isocyanide insertion.
A simple and efficient strategy for the synthesis of indane-1,3-dione derivatives through a palladium(0)-catalyzed reaction incorporating tert-butyl isocyanide has been developed. In addition, by applying this protocol as the key step, indenopyrazole derivatives can be easily synthesized in high yields in a one-pot procedure. This methodology is tolerant of a wide range of substrates and applic...
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With the development of a novel microwave-assisted one-pot tandem de-tert-butylation of tert-butyl amine in an Ugi-type multicomponent reaction product, tert-butyl isocyanide as a useful convertible isonitrile has been explored for the first time affording access to molecular diversity of pharmaceutically-important polycyclic N-fused imidazo-heterocycles.
متن کاملtert-Butyl imidazole-1-carboxylate
In the title compound, C(8)H(12)N(2)O(2), mol-ecules are inter-connected by weak C-H⋯O contacts with H⋯O distances of 2.30 Å, resulting in the formation of chains along [100]. According to graph-set analysis, the unitary descriptor of these chains is C(5). In addition, there are π-π stacking inter-actions between pyrazole rings (centroid distance = 3.878 Å and ring plane distance = 3.26 Å).
متن کاملMetabolically Stable tert-Butyl Replacement.
Susceptibility to metabolism is a common issue with the tert-butyl group on compounds of medicinal interest. We demonstrate an approach of removing all the fully sp(3) C-Hs from a tert-butyl group: replacing some C-Hs with C-Fs and increasing the s-character of the remaining C-Hs. This approach gave a trifluoromethylcyclopropyl group, which increased metabolic stability. Trifluoromethylcyclopro...
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ژورنال
عنوان ژورنال: IUCrData
سال: 2016
ISSN: 2414-3146
DOI: 10.1107/s2414314616003898